| Sl.No. | Name | From | To |
|---|---|---|---|
| 1 | Shri C.R. Pal, IAS | 01.04.1993 | 05.04.1993 |
| 2 | Shri S.C. Mahapatra, IAS | 05.04.1993 | 11.06.1994 |
| 3 | Shri C.B.S.R. RAO,OAS(S) | 12.06.1994 | 01.06.1995 |
| 4 | Shri Srihari Nayak,OAS(S) | 02.06.1995 | 10.03.1997 |
| 5 | Shri S.N. Sarangi,OAS(S) | 10.03.1997 | 22.04.1998 |
| 6 | Shri Lokanath Mishra,IAS | 24.04.1998 | 08.11.1999 |
| 7 | Shri S.C. Mahapatra, IAS | 08.11.1999 | 31.12.1999 |
| 8 | Shri Srikant Ku. Paikray,IAS | 03.01.2000 | 23.06.2003 |
| 9 | Shri R.R. Pattanayak,OAS(S) | 27.06.2003 | 04.11.2006 |
| 10 | Shri Nalini Ku. Burma,OAS(S) | 07.11.2006 | 03.10.2007 |
| 11 | Shri Hrushikesh Tripathy,OAS(SAG) | 03.10.2007 | 10.07.2009 |
| 12 | Shri Krushna Chandra Patra,OAS(SAG) | 14.07.2009 | 02.05.2011 |
| 13 | Shri Akshay Kumar Pani,IAS | 06.05.2011 | 07.04.2013 |
| 14 | Shri Laxminarayan Mishra,IAS | 07.04.2013 | 31.12.2016 |
| 15 | Shri Laxminarayan Mishra,IAS, Commissioner | 01.01.2017 | 31.03.2017 |
| 16 | Dr Gyana Das,IAS | 07.04.2017 | 10.08.2021 |
| 17 | Shri Trilochan Majhi,OAS(SAG) | 11.08.2021 | 20.06.2022 |
| 18 | Shri Siddeshwar Baliram Bondar,IAS | 20.06.2022 | 09.08.2024 AN |
| 19 | Shri Santanu Mohanty,OAS(SAG) | 09.08.2024 AN | 12.08.2024 AN |
| 20 | Shri Dilip Routrai, IAS | 12.08.2024 AN |
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